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Technical
Information
Rechargeable nickel cadmium (Ni-cad) and nickel
metal hydride (Ni-MH) cells are never charged when you receive
them. To obtain
best results follow the manufactures instructions. Always remember
that new cells will require 6-8 full charge / discharge cycles
before reaching full working capacity.
Batteries with light indicators
[gas gauges] such as Bosch 24v/3.0ah and Makita 9.6v/2.0ah can
only be used as a guide to indicate
the remaining working capacity or charging capacity and therefore
should not be used/ accepted as a true reading.
Business experience
to date indicates that our cells will not affect the working
performance of the power tool – Rebatt
only increase the working capacity.
Rule of Thumb
Please note that you cannot always use nickel metal hydride cells
in Ni-Cad chargers unless stated by manufacturer. A charger designed
to service Ni-MH batteries can also accommodate Nickel Cadmium
batteries but NOT the other way around. A Nickel cadmium charger
could overcharge the NI-MH battery pack thus causing overheating
and physical damage.
Quick Charger
Or rapid charger is one of the most popular. It positions itself
between the slow charger and the fast charger. Charging time
for power tool batteries usually takes between 1-3 hours and
the charge rate 0.3C. Charge control is required to terminate
the charge when the battery is fully charged using time information.
The quick-chargers are made to accommodate either nickel based
or lithium based batteries which cannot be interchanged in the
same charger.
Fast [smart] chargers
Is the latest trend on the power tool market which is best suited
to nickel-based batteries. A slow charge rate is known to build
up a crystalline formation known as “memory effect”.
There
are several advantages with this type of rapid charge – Smart
chargers monitor battery current by a rise in temperature to
determine when the battery is fully charged, thereby preventing
over-charging by sensing the rate of temperature increase over
time rather than respond to an absolute temperature.
To terminate
the charge, a temperature increase of 1degrees C [1.8 F] per
minute with an absolute temperature cut-off of 60
degrees C [140 F] “works well” states Buchmann. Some
battery manufacturers encode the cell pack electrically with
more expensive control circuits to identify their chemistry and
rating. The charger then sets the correct charge current and
algorithm for the battery intended.
When a battery is fully charged,
some chargers switch to a topping mode governed by a timer that
completes the charge cycle at a reduced rate until fully charged
before changing to a trickle charge or maintenance charge which compensates for
any self-discharge. This prevents any damage to the battery cells.
One cycle = one full charge and discharge before needing a full
charge again
Cycle charging is a type of charging in which nickel-cadmium batteries
are forcibly cycled one time [a full discharge coupled with a complete
recharge] Cycle chargers normally perform this operation automatically
without any operator initiation.
The useful life of Ni-cad and Ni-MH
cells is usually 1000 charge / discharges which can increase up
to 1400 cycles in certain situations.
However, battery life ends when the battery pack can no longer
provide 80% of its rated capacity after been fully recharged. Approx
life, 18 – 24 months with proper use in the commercial and
professional trade.
Memory Effect
This adverse condition occurs with nickel based battery packs when
the battery cells are only partially discharged many times therefore
a periodic full discharge is so important that “if forgotten” large
crystals will; form on the cell plates referred to as memory effect.
The
crystalline build – up reduces working capacity and the
battery pack will eventually lose its performance if below the
80% needed before been recharged again very quickly. To prevent
memory effect and increase longevity the user should occasionally
[every 120 cycles] fully discharge the battery down to 0.1volts
per cell to remove the crystalline formation from the cell plates.
REBATT UK can offer the reconditioning service on batteries every
120 cycles or every 3 months. The price is £ 2.00 / battery
pack plus p+p. Optimum results are achieved when nickel-based batteries
are reconditioned from NEW.
Lithium – ion / Polymer chargers
Today, the Li-ion is the fastest growing and most promising battery
chemistry. The energy density is typically twice that of the standard
Ni-cad and Ni-MH with the potential to increase the energy density
[voltage] up to 3 times. This type of battery is a low maintenance
battery, an advantage that most other chemistries cannot claim.
There is no memory effect and no scheduled cycling is required
to increase longevity. In addition, the self discharge is less
than half when compared to other chemistries.
No trickle charge
is applied because the li-ion would be unable to absorb the overcharge
as it could cause lithium metal plating
on the anode, a condition that renders the cell unstable.
These
type of chargers have stricter controls in terms of charging methods
and charging time demanded by these batteries. The Li-ion
charger has voltage-limiting device similar to the lead acid battery.
The majority of modern cell packs designed for maximum cycle life
use an end-of-charge voltage threshold of approx 3.8v/cell up to
4.20v/cell when the voltage threshold is reached which is protected
by the protection circuit. The tolerance on all battery packs is
a tight +/- 0.05v / cell.
The li-ion typically discharges to 3.0v/cell.
The spinel and coke versions can be discharged to 2.5v/cell. Caution
should be exercised
not to discharge a lithium-based battery lower than 2.5v/cell as
this may cut off the batteries protection circuit. Similarly, if
the voltage threshold is exceeded during charging the protection
circuit will cut of the voltage to prevent damage and the possibility
of overheating and further damage.
The pulse charge method for
Li-ion has no major advantages and the voltage peaks wreak havoc
with the voltage with the voltage
limiting circuits. While charge times can be reduced, some manufacturers
suggest that pulse charging may shorten the cycle life.
The loss
of charge acceptance of the li-ion / polymer batteries is due to
cell oxidization which occurs during usage and age. Lion
batteries cannot be restored with cycling or deep discharging like
nickel based cells. The capacity loss is permanent because the
metals used in the cells are designated to run for a specific time
only. Service life approx 18 – 24 months on average.
According
to Isidor Buchmann fast charge methods do not significantly decrease
the charge time. A charge rate above 1C should be avoided
because high current can induce lithium plating. With the majority
of modern Lithium ion packs a charge above 1C is not possible due
to the protection circuits limiting the amount of voltage the battery
pack can accept. Li-ion batteries tend to have a slow metabolism
and therefore need to take its time to absorb the energy.
The charge
and discharge current of a battery is measured in C-rate. Most
portable batteries, with the exception of the SLA are rated
at 1C. A discharge of 1C draws a current to the rated capacity.
For example, a battery rated at 1000mAh provides 1ah of use if
discharged at 1C rate. The same battery charged at 0.5C provides
500mAh for 2 hours usage. At 2C the same battery delivers 2000mAh
for 30 min. IC is often referred to as one-hour discharge.
Lithium-based
batteries have a defined age limit. Once the anticipated cycles
have been delivered, no method exists to improve the battery.
The main reason for failure is high internal resistance caused
by oxidization. Operating the battery at elevated temperatures
will momentarily reduce this condition.
When the temperature normalizes,
the condition of high internal resistance returns. If discharged
below 2.5v/cell, the internal
protection circuit often opens. Many of the lithium-ion chargers
cannot apply a recharge and the battery appears to be dead. This
can even happen to fairly new batteries early on during the service
life.
Check with the battery charger manufacturer to establish if
the charger features a booster or wake-up function, to activate
the
protection circuit to enable it to recharge if the battery has
been discharged too low. However, if the cell voltage falls below
1.5v/cell and lower for long periods, a recharge should not be
attempted because of safety concerns with the protection circuit
opening thus cutting off any charge / discharge cycles.
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Did You Know . .
.
It is estimated that 22,000 ton of
batteries was sold in 2002 containing approx 4,000 ton of
re-usable zinc. More facts>> |
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